2017년 12월 23일 토요일

줌달의 일반화학 해답

줌달의 일반화학 해답
줌달의 일반화학 해답.pdf


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A41
Answers to Selected
Exercises
The answers listed here are from the Complete Solutions Guide, in which round-
ing is carried out at each intermediate step in a calculation in order to show
the correct number of signicant gures for that step. Therefore, an answer
given here may differ in the last digit from the result obtained by carrying ex-
tra digits throughout the entire calculation and rounding at the end (the proce-
dure you should follow).
Chapter 1
19. A law summarizes what happens, e.g., law of conservation of mass in a
chemical reaction or the ideal gas law, PV . nRT. A theory (model) is an at-
tempt to explain why something happens. Dalton's atomic theory explains why
mass is conserved in a chemical reaction. The kinetic molecular theory ex-
plains why pressure and volume are inversely related at constant temperature
and moles of gas. 21. The fundamental steps are (1) making observations;
(2) formulating hypotheses; (3) performing experiments to test the hypotheses.
The key to the scientic method is performing experiments to test hypotheses.
If after the test of time, the hypotheses seem to account satisfactorily for some
aspect of natural behavior, then the set of tested hypotheses turns into a the-
ory (model). However, scientists continue to perform experiments to rene or
replace existing theories. 23. A qualitative observation expresses what makes
something what it is; it does not involve a number; e.g., the air we breathe is
a mixture of gases, ice is less dense than water, rotten milk stinks. The SI units
are mass in grams, length in meters, and volume in the derived units of m 3.
The assumed uncertainty in a number is . 1 in the last signicant gure of the
number. The precision of an instrument is related to the number of signicant
gures associated with an experimental reading on that instrument. Different
instruments for measuring mass, length, or volume have varying degrees of
precision. Some instruments only give a few signicant gures for a measure-
ment while others will give more signicant gures. 25. Signicant gures
are the digits we associate with a number. They contain all of the certain dig-
its and the rst uncertain digit (the rst estimated digit). What follows is one
thousand indicated to varying numbers of signicant gures: 1000 or 1 . 103
(1 S.F.); 1.0 . 103 (2 S.F.); 1.00 . 103 (3 S.F.); 1000. or 1.000 . 103 (4 S.F.).
To perform the calculation, the addition/subtraction signicant rule is applied
to 1.5 . 1.0. The result of this is the one signicant gure answer of 0.5. Next,
the multiplication/division rule is applied to 0.5/0.50. A one signicant num-
ber divided by a two signicant number yields an answer with one signicant
gure (answer . 1). 27. The slope of the TF vs. TC plot is 1.8 ( . 9/5) and
the y-intercept is 32 . F. The slope of TC vs. TK plot is 1 and the y-intercept
is . 273. C. 29. a. exact; b. inexact; c. exact; d. inexact 31. a. 3; b. 4; c. 4;
d. 1; e. 7; f. 1; g. 3; h. 3 33. a. 3.42 . 10. 4; b. 1.034 . 104; c. 1.7992 .
101; d. 3.37 . 105 35. a. 641.0; b. 1.327; c. 77.34; d. 3215; e. 0.420
37. a. 188.1; b. 12; c. 4 . 10. 7; d. 6.3 . 10. 26; e. 4.9; Uncertainty appears
in the rst decimal place. The average of several numbers can be only as pre-
cise as the least precise number. Averages can be exceptions to the signicant
gure rules. f. 0.22 39. a. 84.3 mm; b. 2.41 m; c. 2.945 . 10. 5 cm; d. 14.45
km; e. 2.353 . 105 mm; f. 0.9033 . m 41. a. 8 lb and 9.9 oz; ; b. 4.0 .201
4 in
65. 3.8 g/cm 3 67. a. Both are the same mass; b. 1.0 mL mercury; c. Both are
the same mass; d. 1.0 L benzene 69. a. 1.0 kg fe ather; b. 100 g water; c. same
71. 2.77 cm 73. a. Picture iv represents a gaseous compound. Pictures ii and
iii also contain a gaseous compound but have a gaseous element present.
b. Picture vi represents a mixture of two gaseous elements. c. Picture v repre-
sents a solid element. d. Pictures ii and iii both represent a mixture of a gaseous
element and a gaseous compound. 75. a. heterogeneous; b. homogeneous
(hopefully); c. homogeneous; d. homogeneous (hopefully); e. heterogeneous;
f. heterogeneous 77. a. pure; b. mixture; c. mixture; d. pure; e. mixture (cop-
per and zinc); f. pure; g. mixture; h. mixture; i. mixture. Iron and uranium are
elements. Water is a compound. 79. Compound 81. a. physical; b. chemi-
cal; c. physical; d. chemical 83. 24 capsules 85. 15-22 mg/kg 87. Gas:
$62.5; E85: $63.3 89. 7 . 105 kg mercury 91. Chemical changes: b, c,
and d; physical changes: a, e, and f 93. 1.0 . 105 bags 95. 3.0 . 1017 m
97. 56.56. C 99. a. Volume . density . mass; the orange block is more dense.
Since mass (orange) . mass (blue) and volume (orange) . volume (blue), the
density of the orange block must be greater to account for the larger mass of
the orange block. b. Which block is more dense cannot be determined. Since
mass (orange) . mass (blue) and volume (orange) . volume (blue), the den-
sity of the orange block may or may not be larger than the blue block. If the
blue

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