2017년 12월 23일 토요일

줌달의 일반화학 8판 쳅터 7해답

줌달의 일반화학 8판 쳅터 7해답
줌달의 일반화학 8판 쳅터 7해답.pdf


본문
212
CHAPTER 7
ATOMIC STRUCTURE AND PERIODICITY
Questions
19. The equations relating the term s are νλ = c, E = h ν, and E = hc/ λ. From the equations,
wavelength and frequency are inve rsely related, photon energy and frequency are directly
related, and photon energy and wavelength are i nversely related. The unit of 1 Joule (J) = 1
kg m
2
/s
2
. This is why you must change mass units to kg when using the deBroglie equation.
20. Frequency is the number of waves (cycles) of electromagnetic radiation per second that pass
a given point in space. Speed refers to th e distance a wave travels per unit time. All
electromagnetic radiation (EMR) travels at the same speed (c, the speed of light = 2.998 × 10
8
m/s). However, each wavelength of EMR has its own unique frequency,
21. The photoelectric effect refers to the phe nomenon in which electrons are emitted from the
surface of a metal when light strikes it. The light must have a certain minimum frequency
(energy) in order to remove electrons from the surface of a metal. Light having a frequency
below the minimum results in no electrons being emitted, whereas light at or higher than the
minimum frequency does cause electrons to be em itted. For light having a frequency higher
than the minimum frequency, the excess energy is transferred into kinetic energy for the
emitted electron. Albert Einstein explained th e photoelectric effect by applying quantum
theory.
22. The emission of light by excited atoms has been the key interconnection between the
macroscopic world we can observe and measu re, and what is happening on a microscopic
basis within an atom. Excited atoms emit light (which we can observe and measure) because
of changes in the microscopic structure of the atom. By studying the emissions of atoms, we
can trace back to what happened inside the atom. Specifically, our current model of the atom
relates the energy of light emitted to electrons in the atom moving from higher allowed
energy states to lower allowed energy states.
23. Example 7.3 calculates the deBroglie wavelengt h of a ball and of an electron. The ball has a
wavelength on the order of
34
10
m. This is incredibly short and, as far as the wave- particle
duality is concerned, the wave properties of large objects are insignificant. The electron, with
its tiny mass, also has a short wavelength; on the order of
10
10
m. However, this wavelength
is significant because it is on the same order as the spacing between atoms in a typical crystal.
For very tiny objects like electrons, the wave properties are important. The wave properties
must be considered, along with the particle properties, when hypothesizing about the electron
motion in an atom.

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